Search results for "Clock transition"
showing 2 items of 2 documents
Electron-nuclear decoupling at a spin clock transition
2023
The ability to design quantum systems that decouple from environmental noise sources is highly desirable for development of quantum technologies with optimal coherence. The chemical tunability of electronic states in magnetic molecules combined with advanced electron spin resonance techniques provides excellent opportunities to address this problem. Indeed, so-called clock transitions have been shown to protect molecular spin qubits from magnetic noise, giving rise to significantly enhanced coherence. Here we conduct a spectroscopic and computational investigation of this physics, focusing on the role of the nuclear bath. Away from the clock transition, linear coupling to the nuclear degree…
Using optical clock transitions in Cu II and Yb III for time-keeping and search for new physics
2021
We study the $^1$S$_0 - ^3$D$_2$ and $^1$S$_0 - ^3$D$_3$ transitions in Cu II and the $^1$S$_0 - ^3$P$^{\rm o}_2$ transition in Yb III as possible candidates for the optical clock transitions. A recently developed version of the configuration (CI) method, designed for a large number of electrons above closed-shell core, is used to carry out the calculation. We calculate excitation energies, transition rates, lifetimes, scalar static polarizabilities of the ground and clock states, and blackbody radiation shift. We demonstrate that the considered transitions have all features of the clock transition leading to prospects of highly accurate measurements. Search for new physics, such as time va…